Zhenan bao biography sample

Stretchable electronics with proprioceptive feedback may inspire the further development of advanced neuromorphic devices for neurorehabilitation. CLARITY is a tissue preservation and optical clearing technique whereby a hydrogel is formed directly within the architectural confines of ex vivo brain tissue. Raman spectroscopy of individual neurons within hybrids revealed the chemical presence and distribution of polyacrylamide within the mouse hippocampus.

Permeability of F ab '2 secondary fluorescent antibody changes from 9. Notably, protein retention increased linearly relative to standard PFA-fixed tissue from Our quantitative results on polymer distribution, stability, protein retention, and macromolecule permeability can be used to guide the design of future CLARITY-based tissue-clearing solutions, and establish protocols for characterization of novel tissue-polymer hybrid biomaterials using chemical spectroscopy and rheology.

Neurotransmitters play essential roles in regulating neural circuit dynamics both in the central nervous system as well as at the peripheral, including the gastrointestinal tract Their real-time monitoring will offer critical information for understanding neural function and diagnosing disease However, bioelectronic tools to monitor the dynamics of neurotransmitters in vivo, especially in the enteric nervous systems, are underdeveloped.

This is mainly owing to the limited availability of biosensing tools that are capable of examining soft, complex and actively moving organs. NeuroString sensors allow chronic in vivo real-time, multichannel and multiplexed monoamine sensing in the zhenan bao biography sample of behaving mouse, as well as measuring serotonin dynamics in the gut without undesired stimulations and perturbing peristaltic movements.

The described elastic and conformable biosensing interface has broad potential for studying the impact of neurotransmitters on gut microbes, brain-gut communication and may ultimately be extended to biomolecular sensing in other soft organs across the body. Intrinsically stretchable bioelectronic devices based on soft and conducting organic materials have been regarded as the ideal interface for seamless and biocompatible integration with the human body.

A remaining challenge is to combine high mechanical robustness with good electrical conduction, especially when patterned at small feature sizes. We develop a molecular engineering strategy based on a topological supramolecular network, which allows for the decoupling of competing effects from multiple molecular building blocks to meet complex requirements.

We obtained simultaneously high conductivity and crack-onset strain in a physiological environment, with direct photopatternability down to the cellular scale. We further collected stable electromyography signals on soft and malleable octopus and performed localized neuromodulation down to single-nucleus precision for controlling organ-specific activities through the delicate brainstem.

Stretchable polymer semiconductors have advanced rapidly in the past decade as materials required to realize conformable and soft skin-like electronics become available. Through rational molecular-level design, stretchable polymer semiconductor films are now able to retain their electrical functionalities even when subjected to repeated mechanical deformations.

Furthermore, their charge-carrier mobilities are on par with the best flexible polymer semiconductors, with some even exceeding that of amorphous silicon. The key advancements are molecular-design concepts that allow multiple strain energy-dissipation mechanisms, while maintaining efficient charge-transport pathways over multiple length scales.

In this perspective article, we review recent approaches to confer stretchability to polymer semiconductors while maintaining high charge carrier mobilities, with emphasis on the control of both polymer-chain dynamics and thin-film morphology. Additionally, we present molecular design considerations toward intrinsically elastic semiconductors that are needed for reliable device operation under reversible and repeated deformation.

A general approach involving inducing polymer semiconductor nanoconfinement allows for incorporation of several other desired functionalities, such as biodegradability, self-healing, and photopatternability, while enhancing the charge transport. Lastly, we point out future directions, including advancing the fundamental understanding of morphology evolution and its correlation with the change of charge transport under strain, and needs for strain-resilient polymer semiconductors with high mobility retention.

Next-generation light-emitting displays on skin should be soft, stretchable and bright Previously reported stretchable light-emitting devices were mostly basedon inorganic nanomaterials, such as light-emitting capacitors, quantum dots or perovskites They either require high operating voltage or have limited stretchability and brightness, resolution or robustness under strain.

On the other hand, intrinsically stretchable polymer materials hold the promise of good strain tolerance12, However, realizing high brightness remains a grand challenge for intrinsically stretchable light-emitting diodes. Here we report a material design strategy and fabrication processes to achieve stretchable all-polymer-based light-emitting diodes with high brightness about 7,candela per square metrecurrent efficiency about 5.

We fabricate stretchable all-polymer light-emitting diodes coloured red, green and blue, achieving both on-skin wireless powering and real-time displaying of pulse signals. This work signifies a considerable advancement towards high-performance stretchable displays. Smart contact lenses for continuous glucose monitoring CGM have great potential for huge clinical impact.

To date, their development has been limited by challenges in accurate detection of glucose without hysteresis for tear glucose monitoring to track the blood glucose levels. Here, long-term robust CGM in diabetic rabbits is demonstrated by using bimetallic nanocatalysts immobilized in nanoporous hydrogels in smart contact lenses. After redox reaction of glucose oxidase, the nanocatalysts facilitate rapid decomposition of hydrogen peroxide and nanoparticle-mediated charge transfer with drastically improved diffusion via rapid swelling of nanoporous hydrogels.

The ocular glucose sensors result in high sensitivity, fast response time, low detection limit, low hysteresis, and rapid sensor warming-up time. In diabetic rabbits, smart contact lens can detect tear glucose levels consistent with blood glucose levels measured by a glucometer and a CGM device, reflecting rapid concentration changes without hysteresis.

The CGM in a human demonstrates the feasibility of smart contact lenses for further clinical applications. Transient electronics are a rapidly emerging field due to their potential applications in the environment and human health. Recently, a few zhenan bao biographies sample have incorporated acid-labile imine bonds into polymer semiconductors to impart transience; however, understanding of the structure-degradation property relationships of these polymers is limited.

In this study, we systematically design and characterize a series of fully degradable diketopyrrolopyrrole-based polymers with engineered sidechains to investigate the impact of several molecular design parameters on the degradation lifetimes of these polymers. By monitoring degradation kinetics via ultraviolet-visible spectroscopy, we reveal that polymer degradation in solution is aggregation-dependent based on the branching point and Mn, with accelerated degradation rates facilitated by decreasing aggregation.

Additionally, increasing the hydrophilicity of the polymers promotes water diffusion and therefore acid hydrolysis of the imine bonds along the polymer backbone. The aggregation properties and degradation lifetimes of these polymers rely heavily on solvent, with polymers in chlorobenzene taking six times as long to degrade as in chloroform.

We develop a new method for quantifying the degradation of polymers in the thin film and observe that similar factors and considerations e. We found that terpolymerization serves as an attractive approach for achieving degradable semiconductors with both good charge transport and tuned degradation properties. This study provides crucial principles for the molecular design of degradable semiconducting polymers, and we anticipate that these findings will expedite progress toward transient electronics with controlled lifetimes.

Designing a stable solid-electrolyte interphase on a Li anode is imperative to developing reliable Li metal batteries. Li2O nanoparticles suspended in liquid electrolytes were investigated as a proof of concept. Through theoretical and empirical analyses of Li2O suspension electrolytes, the roles played by Li2O in the liquid electrolyte and solid-electrolyte interphases of the Li anode are elucidated.

Also, the suspension electrolyte design is applied in conventional and state-of-the-art high-performance electrolytes to demonstrate its applicability. We expect this design principle and our findings to be expanded into developing electrolytes and solid-electrolyte interphases for Li metal batteries. Various DME-based electrolyte designs have improved long-term cyclability of high-voltage full cells.

However, insufficient Coulombic efficiency at the Li anode and poor high-voltage stability remain a challenge for DME electrolytes. We hypothesized that by substituting the methoxy groups on DME with larger-sized ethoxy groups, the resulting 1,2-diethoxyethane DEE should have a weaker solvation ability and consequently more anion-rich inner solvation shells, both of which enhance interfacial stability at the cathode and anode.

Under stringent full-cell conditions of 4. This work points out a promising path toward the molecular design of non-fluorinated ether-based electrolyte solvents for practical high-voltage Li metal batteries. Shape memory polymers are promising materials in many emerging applications due to their large extensibility and excellent shape recovery.

Here, we report an approach to achieve a high energy density, one-way shape memory polymer based on the formation of strain-induced supramolecular nanostructures. As polymer chains align during strain, strong directional dynamic bonds form, creating stable supramolecular nanostructures and trapping stretched chains in a highly elongated state.

Upon heating, the dynamic bonds break, and stretched chains contract to their initial disordered state. This mechanism stores large amounts of entropic energy as high as The reported phenomenon of strain-induced supramolecular structures offers a new approach toward achieving high energy density shape memory polymers. Redox mediators RMs play a vital role in some liquid electrolyte-based electrochemical energy storage systems.

However, the concept of redox mediator in solid-state batteries remains unexplored. The soluble-type quinone-based RM AQT shows the most favorable redox potential and the best redox reversibility that functions well for lithium sulfide Li2S oxidation in solid polymer electrolytes. In contrast, for bare Li2S cathodes, the solid-solid Li2S-sulfur direct conversion in the first charge cycle results in a high energy barrier for activation charge to 4 V and low sulfur utilization.

This work reveals the evolution of sulfur species in ASSLSBs and realizes the fast Li-S reaction kinetics by designing an effective sulfur speciation pathway. Next-generation wearable electronics require enhanced mechanical robustness and device complexity. Besides previously reported softness and stretchability, desired merits for practical use include elasticity, solvent resistance, facilepatternability and high charge carrier mobility.

Here, we show a molecular design concept that simultaneously achieves all these targeted properties in both polymeric semiconductors and dielectrics, without compromising electrical performance. The high covalent crosslinking density results in both superior elasticity and solvent resistance. The cycling life was stably extended to cycles, five times longer than all reported semiconductors.

Furthermore, we fabricated elastic transistors via consecutively photo-patterning of the dielectric and semiconducting layers, demonstrating the potential of solution-processed multilayer device manufacturing. The iRUM represents a molecule-level design approach towards robust skin-inspired electronics. Early detection of limb ischemia, strokes, and heart attacks may be enabled via long-term monitoring of arterial health.

Early stenosis, decreased blood flow, and clots are common after surgical vascular bypass or plaque removal from a diseased vessel and can lead to the above diseases. Continuous arterial monitoring for the early diagnosis of such complications is possible by implanting a sensor during zhenan bao biography sample that is wirelessly monitored by patients after surgery.

Here, we report the design of a wireless capacitive sensor wrapped around the artery during surgery for continuous post-operative monitoring of arterial health. The sensor responds to diverse artery sizes and extents of occlusion invitro to at least 20cm upstream and downstream of the sensor. It demonstrated strong capability to monitor progression of arterial occlusion in human cadaver and small animal models.

This technology is promising for wireless monitoring of arterial health for pre-symptomatic disease detection and prevention. Bridging polymer design with catalyst surface science is a promising direction for tuning and optimizing electrochemical reactors that could impact long-term goals in energy and sustainability. Particularly, the interaction between inorganic catalyst surfaces and organic-based ionomers provides an avenue to both steer reaction selectivity and promote activity.

We also show that varying the ionomer structure by changing substituents on the imidazolium ring modulates the HER promotion. This ionomer-structure dependence was analyzed via Taft steric parameters and density functional theory calculations, which suggest that steric bulk from functionalities on the imidazolium ring reduces access of the ionomer to both HCO3- and the Ag surface, thus limiting the promotional effect.

Our results help develop design rules for ionomer-catalyst interactions in CO2R and motivate further work into precisely uncovering the interplay between primary and secondary coordination in determining electrocatalytic behavior. Human pluripotent stem cells have emerged as a promising in vitro model system for studying the brain. Two-dimensional and three-dimensional cell culture paradigms have provided valuable insights into the pathogenesis of neuropsychiatric disorders, but they remain limited in their capacity to model certain features of human neural development.

Specifically, current models do not efficiently incorporate extracellular matrix-derived biochemical and biophysical cues, facilitate multicellular spatio-temporal patterning, or achieve advanced functional maturation. Engineered biomaterials have the capacity to create increasingly biomimetic neural microenvironments, yet further refinement is needed before these approaches are widely implemented.

This Review therefore highlights how continued progression and increased integration of engineered biomaterials may be well poised to address intractable challenges in recapitulating human neural development. Strategies to improve stretchability of polymer semiconductors, such as introducing flexible conjugation-breakers or adding flexible blocks, usually result in degraded electrical properties.

In this work, we propose a concept to address this limitation, by introducing conjugated rigid fused-rings with optimized bulky side groups and maintaining a conjugated polymer backbone. Specifically, we investigated two classes of rigid fused-ring systems, namely, benzene-substituted dibenzothiopheno[6,5-b:6',5'-f]thieno[3,2-b]thiophene Ph-DBTTT and indacenodithiophene IDT systems, and identified molecules displaying optimized electrical and mechanical properties.

Our results underscore the intimate correlation between chemical structures, mechanical properties, and charge carrier mobility for polymer semiconductors. Our described molecular design approach will help to expedite the next generation of intrinsically stretchable high-performance polymer semiconductors. Launching a startup company is like synthesizing a new molecule.

There is a starting point and a general concept for how to achieve the desired end. Known steps may be taken, but a successful synthesis is rarely the result of the original plan and relies on perseverance and creativity. If done well, the starting molecule idea gives rise to a new final product business. Having personally lived these journeys, the authors of this viewpoint distilled their combined experiences into relevant topics for scientific entrepreneurs.

This viewpoint is not a how-to guide for launching a startup. Instead, relatable personal insights and potential best practices are shared to catalyze discussions around a topic of growing relevance to both the polymer community and workforce of the future. The electrolyte plays a critical role in lithium-ion batteries, as it impacts almost every facet of a battery's performance.

By measuring open circuit potential in a cell with symmetric electrodes and asymmetric electrolytes, we quantitatively characterize the effects of concentration, anions, and solvents on solvation energy across varied electrolytes. Cryogenic electron microscopy reveals that weaker solvation leads to an anion-derived solid-electrolyte interphase that stabilizes cycling.

Using the potentiometric measurement for characterizing electrolytes, we establish a correlation that can guide the engineering of effective electrolytes for the lithium metal anode. As a key component in stretchable electronics, semiconducting polymers have been widely studied. However, it remains challenging to achieve stretchable semiconducting polymers with high mobility and mechanical reversibility against repeated mechanical stress.

Here, we report a simple and universal strategy to realize intrinsically stretchable semiconducting polymers with controlled multi-scale ordering to address this challenge. Specifically, incorporating two types of randomly distributed co-monomer units reduces overall crystallinity and longer-range orders while maintaining short-range ordered aggregates.

The resulting polymers maintain high mobility while having much improved stretchability and mechanical reversibility compared with the regular polymer structure with only one type of co-monomer units. Interestingly, the crystalline microstructures are mostly retained even under strain, which may contribute to the improved robustness of our stretchable semiconductors.

The proposed molecular design concept is observed to improve the mechanical properties of various p- and n-type conjugated polymers, thus showing the general applicability of our approach. Finally, fully stretchable transistors fabricated with our newly designed stretchable semiconductors exhibit the highest and most stable mobility retention capability under repeated strains of 1, cycles.

Our general molecular engineering strategy offers a rapid way to develop high mobility stretchable semiconducting polymers. Skin-like health care patches SHPs are next-generation health care gadgets that will enable seamless monitoring of biological signals in daily life. Skin-conformable sensors and a stretchable display are critical for the development of standalone SHPs that provide real-time information while alleviating privacy concerns related to wireless data transmission.

However, the production of stretchable wearable displays with sufficient pixels to display this information remains challenging. Here, we report a standalone organic SHP that provides real-time heart rate information. This approach provides a rational strategy for high-resolution stretchable displays, enabling the production of ideal platforms for next-generation wearable health care electronics.

Injectable 3D cell scaffolds possessing both electrical conductivity and native tissue-level softness would provide a platform to leverage electric fields to manipulate stem cell behavior. Granular hydrogels, which combine jamming-induced elasticity with repeatable injectability, are versatile materials to easily encapsulate cells to form injectable 3D niches.

In this work, we demonstrate that electrically conductive granular hydrogels can be fabricated via a simple method involving fragmentation of a bulk hydrogel made from the conducting polymer PEDOT:PSS. Their granular microstructure also enables them to easily encapsulate induced pluripotent stem cell iPSC -derived neural progenitor cells, which were viable for at least 5 days within the injectable gel matrices.

Finally, we demonstrate gel biocompatibility with minimal observed inflammatory response when injected into a rodent brain. Through advances in molecular design, understanding of processing parameters, and development of non-traditional device fabrication techniques, the field of wearable and implantable skin-inspired devices is rapidly growing interest in the consumer market.

Like previous technological advances, economic growth and efficiency is anticipated, as these devices will enable an augmented level of interaction between humans and the environment. However, the parallel growing electronic waste that is yet to be addressed has already left an adverse impact on the environment and human health. Looking forward, it is imperative to develop both human- and environmentally-friendly electronics, which are contingent on emerging recyclable, biodegradable, and biocompatible polymer technologies.

This review provides definitions for recyclable, biodegradable, and biocompatible polymers based on reported literature, an overview of the analytical techniques used to characterize mechanical and chemical property changes, and standard policies for real-life applications. Then, various strategies in designing the next-generation of polymers to be recyclable, biodegradable, or biocompatible with enhanced functionalities relative to traditional or commercial polymers are discussed.

Finally, electronics that exhibit an element of recyclability, biodegradability, or biocompatibility with new molecular design are highlighted with the anticipation of integrating emerging polymer chemistries into future electronic devices. Novel electrolyte designs to further enhance the lithium Li metal battery cyclability are highly desirable.

Here, fluorinated 1,6-dimethoxyhexane FDMH is designed and synthesized as the solvent molecule to promote electrolyte stability with its prolonged -CF2 - backbone. Meanwhile, 1,2-dimethoxyethane is used as a co-solvent to enable higher ionic conductivity and much reduced interfacial resistance. Combining the dual-solvent system with 1 m lithium bis fluorosulfonyl imide LiFSIhigh Li-metal Coulombic efficiency Such high performances are attributed to the anion-derived solid-electrolyte interphase, originating from the coordination of Li-ions to the highly stable FDMH and multiple anions in their solvation environments.

This work demonstrates a new electrolyte design strategy that enables high-performance Li-metal batteries with multisolvent Li-ion solvation with rationally optimized molecular structure and ratio. Owing to their excellent mechanical flexibility, mixed-conducting electrical property, and extraordinary chemical turnability, conjugated polymers have been demonstrated to be an ideal bioelectronic interface to deliver therapeutic effect in many different chronic diseases.

This review article summarizes the latest advances in implantable electronics using conjugated polymers as electroactive materials and identifies remaining challenges and opportunities for developing electronic medicine. Examples of conjugated polymer-based bioelectronic devices are selectively reviewed in human clinical studies or animal studies with the potential for clinical adoption.

The unique properties of conjugated polymers are highlighted and exemplified as potential solutions to address the specific challenges in electronic medicine. Understanding the differences between reactions driven by elevated temperature or electric potential remains challenging, largely due to materials incompatibilities between thermal catalytic and electrocatalytic environments.

This report motivates further studies that quantitatively link catalytic phenomena across disparate reaction environments.

Zhenan bao biography sample

Polymeric electronic materials have enabled soft and stretchable electronics. We present a monolithic optical microlithographic process that directly micropatterns a set of elastic electronic materials by sequential ultraviolet light-triggered solubility modulation. We fabricated transistors with channel lengths of 2 micrometers at a density of 42, transistors per square centimeter.

We fabricated elastic circuits including an XOR gate and a half adder, both of which are essential components for an arithmetic logic unit. Our process offers a route to realize wafer-level fabrication of complex, high-density, and multilayered elastic circuits with performance rivaling that of their rigid counterparts. Depression and anxiety disrupt daily function and their effects can be long-lasting and devastating, yet there are no established physiological indicators that can be used to predict onset, diagnose, or target treatments.

In this review, we conceptualize depression and anxiety as maladaptive responses to repetitive stress. We provide an overview of the role of chronic stress in depression and anxiety and a review of current knowledge on objective stress indicators of depression and anxiety. We focused on cortisol, heart rate variability and skin conductance that have been well studied in depression and anxiety and implicated in clinical emotional states.

A targeted PubMed search was undertaken prioritizing meta-analyses that have linked depression and anxiety to cortisol, heart rate variability and skin conductance. Consistent findings include reduced heart rate variability across depression and anxiety, reduced tonic and phasic skin conductance in depression, and elevated cortisol at different times of day and across the day in depression.

We then provide a brief overview of neural circuit disruptions that characterize particular types of depression and anxiety. We also include an illustrative analysis using predictive models to determine how stress markers contribute to specific subgroups of symptoms and how neural circuits add meaningfully to this prediction. For this, we implemented a tree-based multi-class classification model with physiological markers of heart rate variability as predictors and four symptom subtypes, including normative mood, as target variables.

We then added the neural circuit measures into our predictor set to identify the combination of neural circuit dysfunctions and physiological markers that accurately predict each symptom subtype. Further work to elucidate the complex relationships between physiological markers, neural circuit dysfunction and resulting symptoms would advance our understanding of the pathophysiological pathways underlying depression and anxiety.

Electrolyte-gated transistors EGTscapable of transducing biological and biochemical inputs into amplified electronic signals and stably operating in aqueous environments, have emerged as fundamental building blocks in bioelectronics. In this Primer, the different EGT architectures are described with the fundamental mechanisms underpinning their functional operation, providing insight into key experiments including necessary data analysis and validation.

Several organic and inorganic materials used in the EGT structures and the different fabrication approaches for an optimal experimental design are presented and compared. Relevant and promising applications are discussed, including two-dimensional and three-dimensional cell monitoring, ultra-sensitive biosensors, electrophysiology, synaptic and neuromorphic bio-interfaces, prosthetics and robotics.

Advantages, limitations and possible optimizations are also surveyed. Finally, zhenan bao biography sample issues and future directions for further developments and applications are discussed. In order to apply polymer semiconductors to stretchable electronics, they need to be easily deformed under strain without being damaged.

A small number of conjugated polymers, typically with semicrystalline packing structures, have been reported to exhibit mechanical stretchability. Herein, a method is reported to modify polymer semiconductor packing-structure using a molecular additive, dioctyl phthalate DOPwhich is found to act as a molecular spacer, to be inserted between the amorphous chain networks and disrupt the crystalline packing.

As a result, large-crystal growth is suppressed while short-range aggregations of conjugated polymers are promoted, which leads to an improved mechanical stretchability without affecting charge-carrier transport. Due to the reduced conjugated polymer intermolecular interactions, strain-induced chain alignment and crystallization are observed.

Skin-like intrinsically stretchable soft electronic devices are essential to realize next-generation remote and preventative medicine for advanced personal healthcare The recent development of intrinsically stretchable conductors and semiconductors has enabled highly mechanically robust and skin-conformable electronic circuits or optoelectronic devices2, However, their operating frequencies have been limited to less than hertz, which is much lower than that required for many applications.

Here we report intrinsically stretchable diodes-based on stretchable organic and nanomaterials-capable of operating at a frequency as high as This operating frequency is high enough for the wireless operation of soft sensors and electrochromicdisplaypixels using radiofrequency identification in which the base-carrier frequency is 6.

This was achieved through a combination of rational material design and device engineering. Specifically, we developed a stretchable anode, cathode, semiconductor and current collector that can satisfy the strict requirements for high-frequency operation. Finally, we show the operational feasibility of our diode by integrating it with a stretchable sensor, electrochromicdisplay pixel and antenna to realize a stretchable wireless tag.

This work is an important step towards enabling enhanced functionalities and capabilities for skin-like wearable electronics. Rationally designed pressure sensors for target applications have been in increasing demand. Capacitive pressure sensors with microstructured dielectrics demonstrate a high capability of meeting this demand due to their wide versatility and high tunability by manipulating dielectric layer material and microstructure geometry.

However, to streamline the design and fabrication of desirable sensors, a better understanding of how material microstructure and properties of the dielectric layer affect performance is vital. The ability to predict trends in sensor design and performance simplifies the process of designing and fabricating sensors for various applications. A series of equations are presented that can be used to predict trends in initial capacitance, capacitance change, and sensitivity based on dielectric constant and compressive modulus of the dielectric material and base length, interstructural separation, and height of the dielectric layer microstructures.

The efficacy of this model has been experimentally and computationally confirmed. The model was then used to illuminate, qualitatively and quantitatively, the relationships between these key material properties and microstructure geometries. Finally, this model demonstrates high tunability and simple zhenan bao biography sample for predictive sensor performance for a wide range of designs to help meet the growing demand for highly specialized sensors.

A fundamental challenge, shared across many energy storage devices, is the complexity of electrochemistry at the electrode-electrolyte interfaces that impacts the Coulombic efficiency, operational rate capability, and lifetime. In this work, we take advantage of organic cations with lower reduction potential than lithium to build an electrically responsive polymer interface that not only adapts to morphological perturbations during electrodeposition and stripping but also modulates the lithium ion migration pathways to eliminate surface roughening.

We find that this concept can enable prolonging the long-term cycling of a high-voltage lithium metal battery by at least twofold compared to bare lithium metal. Electrically conductive metal-organic frameworks cMOFs have become a topic of intense interest in recent years because of their great potential in electrochemical energy storage, electrocatalysis, and sensing applications.

FeTHQ exhibited a conductivity of 3. The conductivity of FeTHQ is valence-dependent. A higher conductivity was measured with the as-prepared FeTHQ than with the air-oxidized and sodium naphthalenide-reduced samples. Conductive metal-organic frameworks c-MOFs have drawn increasing attention for their outstanding performance in energy-related applications.

However, the majority of reported c-MOFs are based on 2D structures. Synthetic strategies for 3D c-MOFs are under-explored, leaving unrealized functionality in both their structures and properties. Zn-HAB is shown to have microporosity with a band gap of approximately 1. The power factor of 3. Recently, intrinsically conductive metal-organic frameworks MOFs have demonstrated promising performance in fast-charging energy storage applications and may outperform some current electrode materials e.

Semiconducting single-walled carbon nanotubes swCNTs are a promising class of materials for emerging applications. Read Edit View history. Tools Tools. Download as PDF Printable version. In other projects. Wikimedia Commons Wikidata item. Chemical engineer. In this Chinese namethe family name is Bao. The native form of this personal name is Bao Zhe'nan.

This article uses Western name order when mentioning individuals. NanjingJiangsuChina. Lucent Technologies, Inc. Stanford University. Early life and education [ edit ]. Career [ edit ]. Research [ edit ]. Fellowships and societies [ edit ]. Please help improve it by revising it to be neutral and encyclopedic. July Fellowships [ edit ]. Advisory board positions [ edit ].

Other positions [ edit ]. Awards and honors [ edit ]. Personal life [ edit ]. References [ edit ]. Retrieved 22 May Retrieved 23 February Journal of the Chemical Society, Chemical Communications 6 : — Fellowships and societies [ edit ]. Please help improve it by revising it to be neutral and encyclopedic. July Fellowships [ edit ]. Advisory board positions [ edit ].

Other positions [ edit ]. Awards and honors [ edit ]. Personal life [ edit ]. References [ edit ]. Retrieved 22 May Retrieved 23 February Journal of the Chemical Society, Chemical Communications 6 : — ISSN Bibcode : Natur. PMID Bibcode : MaMol. Angewandte Chemie International Edition in English. Chemistry of Materials. S2CID Advanced Materials.

Bibcode : AdM Journal of the American Chemical Society. Bibcode : JAChS. Retrieved 18 April Applied Physics Letters. Bibcode : ApPhL. ACS Nano.